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Subject: Re: [DCHAS-L] safety of nucleophilic fluorination reagents
Date: Monday, February 26, 2018 at 6:58:10 PM
Author: NEAL LANGERMAN <neal**At_Symbol_Here**CHEMICAL-SAFETY.COM> 		Next by Date:
Subject: Re: [DCHAS-L] Chemical Safety headlines (4 articles)
Date: Mon, 26 Feb 2018 20:26:04 -0500
Author: Samuella Beth Sigmann

From: TILAK CHANDRA <tilak.chandra**At_Symbol_Here**WISC.EDU>
Subject: Re: [DCHAS-L] safety of nucleophilic fluorination reagents
Date: Tue, 27 Feb 2018 01:02:07 +0000
Reply-To: ACS Division of Chemical Health and Safety <DCHAS-L**At_Symbol_Here**PRINCETON.EDU>
Message-ID: DM5PR06MB3195770D43CA99EC1E19321A88C00**At_Symbol_Here**DM5PR06MB3195.namprd06.prod.outlook.com
In-Reply-To


Hi Kristi:

 

There is a low probability of generating HF as a side product during nucleophilic fluorination. By the way which method researcher is using for forming the C-F bond? There are various methods available in the literature for such fluorination.

 

http://www.scripps.edu/baran/images/grpmtgpdf/Su_May_08.pdf

 

Good luck.

 

Tilak

From: ACS Division of Chemical Health and Safety <DCHAS-L**At_Symbol_Here**PRINCETON.EDU> on behalf of Kristi Ohr <kohr**At_Symbol_Here**UMASS.EDU>
Sent: Monday, February 26, 2018 5:06:04 PM
To: DCHAS-L**At_Symbol_Here**PRINCETON.EDU
Subject: [DCHAS-L] safety of nucleophilic fluorination reagents
 

Is anyone else treating nucleophilic fluorination reagents in the same way as HF in terms of precautions and emergency response?  I'm not finding any data on the subject aside from recommendations to have calcium gluconate on hand in SDSs.

 

Thanks,

 

Kristi

 

Kristi Ohr, Ph.D.
Chemical Safety Services Manager

Environmental Health and Safety
UMass Amherst
40 Campus Center Way
Draper Hall
Amherst, MA 01003
Office: 413-545-5117

Cell: 413-800-4408

kohr**At_Symbol_Here**ehs.umass.edu

www.ehs.umass.edu

 

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