From: NEAL LANGERMAN <neal**At_Symbol_Here**CHEMICAL-SAFETY.COM>
Subject: Re: [DCHAS-L] New procedure for transferring tert-butyllithium from Sure/Seal bottles
Date: Tue, 12 Jun 2018 07:41:36 -0700
Reply-To: neal**At_Symbol_Here**CHEMICAL-SAFETY.COM
Message-ID: 012d01d4025b$77717230$66545690$**At_Symbol_Here**chemical-safety.com
In-Reply-To


Jyllian

The device will perform well for 1 mL titrations and perhaps up to 10 mL reactions, beyond that it will be difficult to use and offer no advantage over a canula.

The device will require some practice to learn to use and careful attention to proper procedure - that is to say, it will need operator training.

Finally, it has an equipment barrier to use that a lab will need to commit to overcoming.

 

Bottom line - I see an incremental advantage for small scale pyrophor use. For the application described - a teaching lab, it does make sense.

 

Thanks for bringing this to our attention.

 

Neal

 

 

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From: ACS Division of Chemical Health and Safety <DCHAS-L**At_Symbol_Here**PRINCETON.EDU> On Behalf Of Jyllian Kemsley
Sent: Tuesday, June 12, 2018 7:06 AM
To: DCHAS-L**At_Symbol_Here**PRINCETON.EDU
Subject: [DCHAS-L] New procedure for transferring tert-butyllithium from Sure/Seal bottles

 

Hi all,

 

Curious to know what people think of the tBuLi transfer procedure proposed in this paper just accepted by OPRD:

 

Compared to, say, the one in the ChemUCSD videos:

 

Thanks!

Jyllian

 

Jyllian Kemsley, Ph.D.

Executive Editor, Policy

Chemical & Engineering News

Phone:  (+1) 925-519-6681 (office, mobile, messaging apps)

Skype: jyllian.kemsley

Twitter: **At_Symbol_Here**jkemsley

 

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